A FACILE SYNTHESIS OF 1,4-DIKETONES

被引:24
作者
BERGMAN, R [1 ]
NILSSON, B [1 ]
WICKBERG, B [1 ]
机构
[1] LUND INST TECHNOL, POB 124, S-22100 LUND, SWEDEN
关键词
D O I
10.1016/S0040-4039(00)94698-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
1,4-Diketones may conveniently be synthesized by the addition of 2-methylcyclopropenyllithium to N-methoxy-N-methylcarboxamides followed by hydrolysis of intermediate cyclopropyl ketone adducts on silica gel. The new method has been applied to the synthesis of cis-jasmone. © 1990.
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页码:2783 / 2786
页数:4
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