KINETIC AND COMPUTER MODELING OF EPOXY-RESIN CURE

被引：9

作者：

BUIST, GJ

HAGGER, AJ

HOWLIN, BJ

JONES, JR

PARKER, MJ

BARTON, JM

WRIGHT, WW

机构：

[1] UNIV SURREY,DEPT CHEM,STRUCT & COMP CHEM RES GRP,GUILDFORD GU2 5XH,SURREY,ENGLAND

[2] ROYAL AIRCRAFT ESTAB,DEF RES AGCY,DIV AEROSP,FARNBOROUGH GU14 6TD,HANTS,ENGLAND

来源：

COMPUTERS & CHEMISTRY | 1993年 / 17卷 / 03期

关键词：

D O I：

10.1016/0097-8485(93)80004-W

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of a combination of computer modelling and tritium radiolabeling is described as a technique for the investigation of the kinetics and mechanism of the autocatalytic reactions occurring in epoxy resin cure. Rate constants for substituted anilines reacting with phenylglycidylether have been derived and the effect of steric hindrance investigated. The program is described and its use in the explanation and understanding of the experimental data is illustrated.

引用

页码：257 / 263

页数：7

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ALPER J, 1989, POLYM MATERIALS CHEM

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[4]

ARUTYUNYAN KA, 1974, ZH FIZ KHIM+, V48, P2896