BIS(1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONATO)(1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE)BARIUM

被引：10

作者：

INEROWICZ, HD

KHAN, MA

ATKINSON, G

WHITE, RL

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193011072

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, [Ba(C5HF6O2)2(C12H2N2O4)], the Ba2+ cation is ten-coordinated by four O and two N atoms from a crown ether, and by four O atoms from two beta-diketone ligands. Ba-O and Ba-N distances range from 2.75 to 3.00 angstrom. The Ba atom is located near the center and 1.343 (1) angstrom above the mean plane of the crown ether. The two beta-diketone ligands are located on the same side of the complex. There are no significant intermolecular contacts.

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页码：688 / 690

页数：3

相关论文

共 9 条

[1] THE X-RAY CRYSTAL-STRUCTURES OF [CA(HFA)2(OH2)2] AND [BA(HFA)2(OH2)] (HHFA=1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONE) [J].

BRADLEY, DC ;

HASAN, M ;

HURSTHOUSE, MB ;

MOTEVALLI, M ;

KHAN, OFZ ;

PRITCHARD, RG ;

WILLIAMS, JO .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (07) :575-576

[2]

HERCEG M, 1972, B SOC CHIM FR, P549

[3]

JOHNSON CK, 1965, ORNL3794 REP

[4] VOLATILE BARIUM, STRONTIUM AND CALCIUM BIS(HEXAFLUOROACETYLACETONATE)(CROWN ETHER) COMPLEXES [J].

NORMAN, JAT ;

PEZ, GP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (14) :971-972

[5]

SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

[6]

SHELDRICK GM, 1905, SHELXS86 PROGRAM SOL

[7] STRUCTURE OF BIS(1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONATO)-(2,5,8,11,14-PENTAOXAPENTADECANE)BARIUM(II) [J].

VANDERSLUIS, P ;

SPEK, AL ;

TIMMER, K ;

MEINEMA, HA .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :1741-1743

[8] OLIGOETHER COMPLEXES OF ALKALINE-EARTH METAL-IONS .1. STRUCTURES OF 2,5,8,11,14-PENTAOXAPENTADECANE (TETRAGLYME) COMPLEXED WITH CALCIUM, STRONTIUM AND BARIUM THIOCYANATES [J].

WEI, YY ;

TINANT, B ;

DECLERCQ, JP ;

VANMEERSSCHE, M ;

DALE, J .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :1076-1080

[9] CROWN ETHER COMPLEXES OF ALKALINE-EARTH METAL-IONS .3. STRUCTURES OF 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE (18-CROWN-6) COMPLEXES WITH MAGNESIUM AND BARIUM THIOCYANATES [J].

WEI, YY ;

TINANT, B ;

DECLERCQ, JP ;

VANMEERSSCHE, M ;

DALE, J .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :77-80