THERMAL-ISOMERIZATION OF INDIGO

被引：35

作者：

HAUCKE, G

GRANESS, G

机构：

[1] Institut für Physikalische Chemie, Universität Jena, D-07743

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 01期

关键词：

INDIGO; ISOMERIZATION; SEMIEMPIRICAL CALCULATIONS; SPECTROSCOPY;

D O I：

10.1002/anie.199500671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

At about 460°C indigo (1) isomerizes to dibenzonaphthyridindione (2) in the gas phase remarkably smoothly with ring enlargement to incorporate the central CC double bond. The transition state was calculated (PM3) and is characterized by the rupture of the bonds between the carbonyl groups and the central CC unit. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：67 / 68

页数：2

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