COMPOUNDS OF GERMANIUM AND TIN .11. NEW 4-MEMBERED RINGS - THIATRIGERMETANE, SELENATRIGERMETANE AND N-PHENYLTRIGERMACYCLOBUTANIMINE

被引：15

作者：

WEIDENBRUCH, M ^{[1
]}

RITSCHL, A ^{[1
]}

PETERS, K ^{[1
]}

VONSCHNERING, HG ^{[1
]}

机构：

[1] MAX PLANCK INST FESTKORPERFORSCH,W-7000 STUTTGART 80,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 438卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(92)88004-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of hexa-t-butylcyclotrigermane (7) with sulfur or selenium gives the ring-enlarged molecules thiatrigermetane (8) and selenatrigermetane (9), respectively. Phenyl isocyanide reacts similarly by insertion of the carbene-like carbon atom into one Ge-Ge bond of 7 to provide the trigermacyclobutanimine derivative 10. The X-ray structure analysis of 9 reveals a strictly planar four-membered ring with elongated Ge-Ge bonds.

引用

页码：39 / 44

页数：6

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