SYNTHESES AND ELECTRONIC-STRUCTURES OF DECAMETHYLMANGANOCENES

被引：91

作者：

ROBBINS, JL ^{[1
]}

EDELSTEIN, NM ^{[1
]}

COOPER, SR ^{[1
]}

SMART, JC ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 14期

关键词：

D O I：

10.1021/ja00508a023

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses of [(C5(CH3)5)2Mn]PF6, (C5(CH3)5)2Mn, and Na[(C5(CH3)5)2Mn] are described. Magnetic susceptibility, infrared, electrochemical, N MR, and reactivity studies suggest the formulation of these complexes as low-spin 16-, 17-, and 18-electron planar metallocenes. EPR spectra of the neutral complex are consistent with the 2E2g configuration determined for other low-spin 17-electron metallocenes. © 1979, American Chemical Society. All rights reserved.

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页码：3853 / 3857

页数：5

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