SYNTHESIS AND CHARACTERIZATION OF A THERMALLY ROBUST TITANIUM DINITROGEN COMPLEX - THE CRYSTAL-STRUCTURE OF [([(ME3SI)2N]TICL(PYRIDINE)2)2(MU-ETA-ETA'-N2)]

被引：39

作者：

BEYDOUN, N ^{[1
]}

DUCHATEAU, R ^{[1
]}

GAMBAROTTA, S ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 6N5,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000244

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of trans-[TiCl2(tmeda)2] (tmeda = N, N, N', N'-tetramethylethylenediamine) with one equivalent of LiN(Me3Si)2, followed by treatment with pyridine, led to the formation of a novel Ti-dinitrogen complex [{TiCl[N(SiMe3)2](pyridine)2}(pyridine)2}2(mu-eta:eta'-N2)].

引用

页码：244 / 246

页数：3

共 34 条

[1] ACETYLENE DERIVATIVES OF TITANOCENE
ALT, HG
ENGELHARDT, HE
RAUSCH, MD
KOOL, LB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (12) : 3717 - 3718
[2] TITANOCENE AS AN INTERMEDIATE IN REACTIONS INVOLVING MOLECULAR-HYDROGEN AND NITROGEN
BERCAW, JE
BELL, LG
BRINTZIN.HH
MARVICH, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (04) : 1219 - &
[3] MOLECULAR-STRUCTURE OF (CP2TI(PME3))2(MU-N2), A TITANOCENE DINITROGEN COMPLEX
BERRY, DH
PROCOPIO, LJ
CARROLL, PJ
[J]. ORGANOMETALLICS, 1988, 7 (02) : 570 - 572
[4] TITANIUM HEXACARBONYL, TI(CO)6, AND TITANIUM HEXADINITROGEN, TI(N2)6 .1. SYNTHESIS USING TITANIUM ATOMS AND CHARACTERIZATION BY MATRIX IR AND ULTRAVIOLET-VISIBLE SPECTROSCOPY
BUSBY, R
KLOTZBUCHER, W
OZIN, GA
[J]. INORGANIC CHEMISTRY, 1977, 16 (04) : 822 - 828
[5] TITANACYCLES DERIVED FROM REDUCTIVE COUPLING OF NITRILES, ALKYNES, ACETALDEHYDE, AND CARBON-DIOXIDE WITH BIS(PENTAMETHYLCYCLOPENTADIENYL)(ETHYLENE)TITANIUM(II)
COHEN, SA
BERCAW, JE
[J]. ORGANOMETALLICS, 1985, 4 (06) : 1006 - 1014
[6] STRUCTURE AND REACTIVITY OF BIS(PENTAMETHYLCYCLOPENTADIENYL)(ETHYLENE)TITANIUM(II), A SIMPLE OLEFIN ADDUCT OF TITANIUM
COHEN, SA
AUBURN, PR
BERCAW, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (05) : 1136 - 1143
[7] Demerseman B., 1985, J ORGANOMET CHEM, V297, pC35
[8] CARBON-CARBON DOUBLE-BOND FORMATION IN THE INTERMOLECULAR ACETONITRILE REDUCTIVE COUPLING PROMOTED BY A MONONUCLEAR TITANIUM(II) COMPOUND - PREPARATION AND CHARACTERIZATION OF 2 TITANIUM(IV) IMIDO DERIVATIVES
DUCHATEAU, R
WILLIAMS, AJ
GAMBAROTTA, S
CHIANG, MY
[J]. INORGANIC CHEMISTRY, 1991, 30 (25) : 4863 - 4866
[9] FORMATION AND CHARACTERIZATION OF ETA-2-IMINE AND ETA-2-AZOBENZENE DERIVATIVES OF TITANIUM CONTAINING ANCILLARY ARYLOXIDE LIGATION
DURFEE, LD
HILL, JE
FANWICK, PE
ROTHWELL, IP
[J]. ORGANOMETALLICS, 1990, 9 (01) : 75 - 80
[10] REDUCTIVE ELIMINATION PATHWAYS TO LOW-VALENT TITANIUM ARYLOXIDE COMPLEXES
DURFEE, LD
FANWICK, PE
ROTHWELL, IP
FOLTING, K
HUFFMAN, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (15) : 4720 - 4722

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