STUDIES ON TSUSHIMYCIN .2. STRUCTURES OF CONSTITUENT FATTY ACIDS

被引：14

作者：

SHOJI, J

OTSUKA, H

机构：

[1] Shionogi Research Laboratory, Shionogi … Co. Ltd., Osaka, Fukushima-ku

来源：

JOURNAL OF ANTIBIOTICS | 1969年 / 22卷 / 10期

关键词：

D O I：

10.7164/antibiotics.22.473

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

The constituent fatty acids of the antibiotic tsushimycin were examined by gas-liquid chromatography, mass spectrometry, nuclear magnetic resonance and infrared spectroscopy. Also, periodate-permanganate oxidation unequivocally indicated the position of double bonds. The structures of two major constituent fatty acids were determined as cis-3-isotetradecenoic acid and cis-3-anteisopentadecenoic acid. As a result of parallel experiments, the main constituent fatty acid of the antibiotic amphomycin was also elucidated as cis-3-anteisotridecenoic acid. © 1969, JAPAN ANTIBIOTICS RESEARCH ASSOCIATION. All rights reserved.

引用

页码：473 / &

共 12 条

[1] STRUCTURAL CORRELATION OF UNSATURATED FATTY ACID ESTERS THROUGH GRAPHICAL COMPARISON OF GAS--LIQUID CHROMATOGRAPHIC RETENTION TIMES ON A POLYESTER SUBSTRATE [J].