BINDING OF AMINO-ACIDS IN WATER TO A HIGHLY ELECTRON-RICH AROMATIC CAVITY OF PYROGALLOL OR RESORCINOL CYCLIC TETRAMER AS PI-BASE

被引：36

作者：

KOBAYASHI, K ^{[1
]}

TOMINAGA, M ^{[1
]}

ASAKAWA, Y ^{[1
]}

AOYAMA, Y ^{[1
]}

机构：

[1] NAGAOKA UNIV TECHNOL,DEPT CHEM,NAGAOKA,NIIGATA 94021,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 32期

关键词：

HOST-GUEST INTERACTION; AMINO ACID; HYDROPHOBIC EFFECT; PI-BASICITY; CH-PI INTERACTION;

D O I：

10.1016/S0040-4039(00)60692-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tetrasulfonated derivatives of pyrogallol or resorcinol cyclic tetramer form a 1:1 complex in water with not only aromatic but also relatively hydrophobic aliphatic amino acids. The stability of the complex depends on both the hydrophobicity of the guest and the pi-basicity of the host.

引用

页码：5121 / 5124

页数：4

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