THE 1ST NEUTRAL ADAMANTANOID IRON(III)-CHELATE COMPLEX - SPONTANEOUS FORMATION, STRUCTURE, AND ELECTROCHEMISTRY

被引：91

作者：

SAALFRANK, RW

HORNER, B

STALKE, D

SALBECK, J

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY

[2] UNIV REGENSBURG,INST ORGAN CHEM,W-8400 REGENSBURG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 08期

关键词：

D O I：

10.1002/anie.199311791

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

''Metalloautism''-this term perfectly describes the characteristic of the adamantanoid iron(III) chelate complex 1 that the four iron centers do not interact with each other either electronically or magnetically. The four metal atoms are linked by six chelatino ligands (2), which are prepared by deprotonation of the product of the condensation of terephthaloyl chloride and dimethyl malonate.

引用

页码：1179 / 1182

页数：4

共 54 条

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