IONIZATION-POTENTIALS OF CAF AND BAF

被引：21

作者：

JAKUBEK, ZJ

HARRIS, NA

FIELD, RW

GARDNER, JA

MURAD, E

机构：

[1] PHILLIPS LAB,WSSI,PHOTOMETR INC,29 RANDOLPH RD,BEDFORD,MA 01731

[2] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

[3] PHOTOMETR INC,WOBURN,MA 01801

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 01期

关键词：

D O I：

10.1063/1.466923

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Although the alkaline earth-monohalide compounds, MX, have been extensively studied, their ionization potentials to MX+ are only known to within a few tenths of an eV. Using an improved electron impact ionization potential measurement to assist in arranging spectroscopic vibronic band origins into Rydberg series, we report high precision ionization potential measurements for CaF and BaF to be IP(CaF) = 5.8270 +/- 0.0006 eV and IP(BaF) = 4.8034 +/- 0.0004 eV. The synergism between the electron impact method and the spectroscopic method is detailed, and the minimum accuracy required of the electron impact data is assessed.

引用

页码：622 / 627

页数：6

共 17 条

[1]

Belyaev V.N., 1990, RUSS J PHYS CHEM, V64, P773

[2]

BERG JM, IN PRESS PHYS REV A

[3]

Chase Jr M. W., 1985, J PHYS CHEM REF D S1, V14

[4]

Gaydon A. G., 1953, DISSOCIATION ENERGIE

[5]

Herzberg G., 1950, SPECTRA DIATOMIC MOL

[6]

Huber K. P., 1979, CONSTANTS DIATOMIC M, DOI DOI 10.1007/978-1-4757-0961-2_2

[7]

JAKUBEK Z, UNPUB

[8] THERMOCHEMICAL STUDIES OF THE BF2 RADICAL [J].

LAU, KH ;

HILDENBRAND, DL .

JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (09) :4928-4931

[9]

LEVIN RD, 1982, NBS NAT STAND REF DA, V71

[10] RYDBERG STATES AND IONIZATION-POTENTIAL OF CALCIUM MONOFLUORIDE [J].

MURPHY, JE ;

BERG, JM ;

MERER, AJ ;

HARRIS, NA ;

FIELD, RW .

PHYSICAL REVIEW LETTERS, 1990, 65 (15) :1861-1864

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