PHYSICOCHEMICAL PROPERTIES OF DY-3+ IN SINGLE KY(MOO4)2 CRYSTAL (ELECTRON ABSORPTION, EMISSION, IR, RAMAN, AND MAGNETIC DATA)

被引：16

作者：

HANUZA, J ^{[1
]}

MACALIK, L ^{[1
]}

RYBAROMANOWSKI, W ^{[1
]}

MUGENSKI, E ^{[1
]}

CYWINSKI, R ^{[1
]}

WITKE, K ^{[1
]}

PILTZ, W ^{[1
]}

REICH, P ^{[1
]}

机构：

[1] ACAD SCI GDR,INST PHYS CHEM,DDR-1086 BERLIN,GER DEM REP

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1988年 / 73卷 / 02期

关键词：

CRYSTALS - Lattice Vibrations - ELECTRONS - Absorption - LUMINESCENCE - MAGNETIC PROPERTIES - SPECTROSCOPY - Applications;

D O I：

10.1016/0022-4596(88)90135-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electron absorption, luminescence, vibrational, and magnetic properties of KDy//xY//1// minus //x(MoO//4)//2 crystals are examined over the entire concentration region x equals 0 to x equals 1 and a temperature range 13-293 K. The crystal field scheme of the **6H, **6F, **4F, **4I manifolds and their Stark components are established. The tau // lambda Judd-Ofelt parameters are determined by the numerical method and related to the concentration effect. The temperature dependence of the lifetime of luminescence is discussed and a quenching mechanism is proposed.

引用

页码：488 / 501

页数：14

共 33 条

[1] CALCULATION OF CRYSTAL-FIELD SPLITTING OF SM3+ AND DY3+ LEVELS IN LACL3 WITH INCLUSION OF J MIXING [J].

AXE, JD ;

DIEKE, GH .

JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (10) :2364-&

[2] SPECTROPHOTOMETRIC DETERMINATION OF RARE EARTH MIXTURES [J].

BANKS, CV ;

KLINGMAN, DW .

ANALYTICA CHIMICA ACTA, 1956, 15 (04) :356-363

[3] ELECTRONIC ENERGY LEVELS IN TRIVALENT LANTHANIDE AQUO IONS .I. PR3+ ND3+ PM3+ SM3+ DY3+ HO3+ ER3+ AND TM3+ [J].

CARNALL, WT ;

FIELDS, PR ;

RAJNAK, K .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4424-&

[4] SPECTRAL INTENSITIES OF TRIVALENT LANTHANIDES AND ACTINIDES IN SOLUTION .2. PM3+ SM3+ EU3+ GD3+ TB3+ DY3+ AND HO3+ [J].

CARNALL, WT ;

FIELDS, PR ;

RAJNAK, K .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (10) :4412-&

[5] SPECTRUM AND MAGNETIC PROPERTIES OF HEXAGONAL DYCL3 [J].

CROSSWHITE, H ;

DIEKE, GH .

JOURNAL OF CHEMICAL PHYSICS, 1961, 35 (05) :1535-&

[6] THE MAGNETIC PROPERTIES OF CERTAIN RARE-EARTH ETHYL SULPHATES [J].

ELLIOTT, RJ ;

STEVENS, KWH .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1953, 219 (1138) :387-404

[7] THE LOW-TEMPERATURE SPECTRA AND NORMAL COORDINATE ANALYSIS OF KY(MOO4)2 CRYSTAL [J].

HANUZA, J ;

BURGINA, EB ;

OSIPOVA, GA ;

YURCHENKO, EN .

JOURNAL OF MOLECULAR STRUCTURE, 1987, 158 :141-152

[8] POLARIZED RAMAN AND INFRARED-SPECTRA OF A MULTILAYER KY (MOO4)2 CRYSTAL [J].

HANUZA, J ;

LABUDA, L .

JOURNAL OF RAMAN SPECTROSCOPY, 1981, 11 (04) :231-237

[9] POLARIZED IR AND RAMAN-SPECTRA OF KDY(MOO4)2 SINGLE-CRYSTALS, AND THE MO-92-MO-100 ISOTOPE EFFECT [J].

HANUZA, J ;

FOMITSEV, VV .

JOURNAL OF MOLECULAR STRUCTURE, 1980, 66 (SEP) :1-24

[10] POLARIZED IR AND RAMAN-SPECTRA OF ORTHORHOMBIC KLN(MOO4)2 CRYSTALS (LN=Y,DY,HO,ER,TM,YB,LU) [J].

HANUZA, J ;

MACALIK, L .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1982, 38 (01) :61-72

← 1 2 3 4 →