SYNTHESIS AND POLYMERIZATION OF ALKYL ALPHA-(PHENOXYMETHYL)ACRYLATES

被引：42

作者：

LENZ, RW ^{[1
]}

SAUNDERS, K ^{[1
]}

BALAKRISHNAN, T ^{[1
]}

HATADA, K ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN SCI,DEPT CHEM,OSAKA,JAPAN

来源：

MACROMOLECULES | 1979年 / 12卷 / 03期

关键词：

D O I：

10.1021/ma60069a008

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Methyl and ethyl α-(phenoxymethyl) acrylate were synthesized and polymerized by free-radical initiators at 60 and -50 °C. The polymers were of relatively low molecular weight, and analysis by NMR spectroscopy indicated that they were almost perfectly atactic in structure. There was little or no effect of polymerization temperature on yield, molecular weight, molecular weight distribution, or tacticity. As expected, the glass transition temperatures of the polymers were higher than those of the comparable methacrylate and α-chloroacrylate polymers. © 1979, American Chemical Society. All rights reserved.

引用

页码：392 / 394

页数：3

共 16 条

[1] STEREOCHEMICAL CONFIGURATION OF VINYL POLYMERS AND ITS OBSERVATION BY NUCLEAR MAGNETIC RESONANCE [J].