LOCALIZATION OF OPTICAL-EXCITATIONS IN CRYSTALLINE RH-3+-TRISDIIMINE CHELATES

被引：26

作者：

WESTRA, J

GLASBEEK, M

机构：

[1] Laboratory for Physical Chemistry, University of Amsterdam, 1018 WS Amsterdam

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 166卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(90)87147-J

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The luminescent state of [Rh(bpy)3](ClO4)3 (bpy = 2,2′-bipyridine) has been studied by means of low-field optically detected magnetic resonance (ODMR) spectroscopy. Experiments performed on single crystals, at low temperatures (T ≈ 1.4 K), revealed a magnetic anisotropy characteristic of a ligand-centered 3π-π* excitation. Furthermore, the experimental results show that the excitation is trapped on one single ligand molecule per Rh3+ cation site only. © 1990.

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页码：535 / 538

页数：4

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