CRYSTAL-STRUCTURE OF THE ORGANIC METAL (DMET)2BF4 WITH 2 COLUMNS ALONG 2 CRYSTALLOGRAPHIC AXES

被引：16

作者：

ISHIKAWA, Y

SAITO, K

KIKUCHI, K

KOBAYASHI, K

IKEMOTO, I

机构：

[1] TOKYO METROPOLITAN UNIV, FAC SCI, DEPT CHEM, SETAGAYA KU, TOKYO 158, JAPAN

[2] UNIV TOKYO, COLL ARTS & SCI, DEPT CHEM, MEGURO KU, TOKYO 153, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 01期

关键词：

D O I：

10.1246/bcsj.64.212

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of (DMET)2BF4: 5,6-dihydro-2-(4,5-dimethyl-1,3-diselenol-2-ylidene)dithiolo[4,5-b] [1,4]dithiinium tetrafluoroborate (2:1), (C10H10S4Se2)2BF4, is determined. Crystal data: M(r) = 919.49, triclinic, P1, a = 7.032(2), b = 7.812(3), c = 27.502(11) angstrom, alpha = 90.87(2), beta = 90.28(2), gamma = 106.22(2)-degrees, V = 1450.5(15) angstrom3, Z = 2, D(x) = 2.11 Mg m-3, lambda(Mo K-alpha) = 0.71068 angstrom, mu = 5.60 mm-1, F(000) = 890, T = 297 K, R = 0.077 for 4600 reflections. Two crystallographically independent DMET molecules separately form columns along nearly perpendicular directions, and ordered BF4 anions are located between the DMET columns.

引用

页码：212 / 215

页数：4

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