CRYSTAL STRUCTURE OF A DIACID TRIGLYCERIDE

被引:27
作者
DOYNE, TH
GORDON, JT
机构
[1] Department of Chemistry, Villanova University, Villanova, 19085, Pennsylvania
关键词
D O I
10.1007/BF02667104
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The x-ray structure analysis of a single crystal of the β-@#@ form of 2-11-bromoundecanoyl-l, 1 - dicaprin has revealed an arrangement of carbon atom chains within a molecular layer that is identical to that found in the β-form monoacid triglycerides. However the packing of the molec-ular layers within the crystal lattice is sub-stantially different because of the unequal fatty acid chain-lengths in the symmetrical diacid triglyceride of this investigation. Insufficient diffraction data owing to difficulty in preparing crystals of adequate size prohibits computation of precise interatomic distances and angles for this triglyceride. © 1968 American Oil Chemists' Society.
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页码:333 / &
相关论文
共 8 条
  • [1] CHAPMAN D, 1962, CHEM REVS, V62, P444
  • [2] GLYCERIDE SYNTHESIS BY DIRECT ESTERIFICATION
    HARTMAN, L
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1957, (AUG): : 3572 - 3575
  • [3] CRYSTAL STRUCTURE OF BETA-TRICAPRIN
    JENSEN, LH
    MABIS, AJ
    [J]. NATURE, 1963, 197 (486) : 681 - &
  • [4] REFINEMENT OF STRUCTURE OF BETA-TRICAPRIN
    JENSEN, LH
    MABIS, AJ
    [J]. ACTA CRYSTALLOGRAPHICA, 1966, 21 : 770 - &
  • [5] KITAIGORODSKII AI, 1961, ORGANIC CHEM CRYSTAL, P177
  • [6] LARSSON K, 1963, P CHEM SOC LONDON, P87
  • [7] LARSSON K, 1964, ARKIV KEMI, V23, P41
  • [8] LARSSON K, 1964, ARK KEMI, V23, P1