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EFFECT OF PRESSURE ON OXIDATION STATE OF FERRATES

被引：6
作者：
PANYUSHKIN, VN
DEPASQUALI, G
DRICKAMER, HG
机构：
[1] Department of Physics, Materials Research Laboratory, University of Illinois, Urbana
来源：
JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 08期
关键词：
D O I：
10.1063/1.1672512
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The effect of pressure has been studied on the oxidation state of Fe(IV) in SrFeO289 and of Fe(VI) in BaFeO4-x. Fe(IV) reduces to Fe(III) with increasing pressure, and Fe(VI) reduces to Fe(IV) with perhaps some production of Fe (III). The first process is reversible but the second is not. In neither case does the simple relationship between concentration and pressure found for the reversible reduction of Fe(III) to Fe(II) hold.
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页码：3305 / +
页数：1
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