DYNAMICS OF HYDROGEN ABSTRACTION FROM POLYATOMIC-MOLECULES BY FLUORINE-ATOMS

被引:33
作者
MACDONALD, RG [1 ]
SLOAN, JJ [1 ]
WASSELL, PT [1 ]
机构
[1] NATL RES COUNCIL CANADA, DIV CHEM, OTTAWA K1A 0R6, ONTARIO, CANADA
关键词
D O I
10.1016/0301-0104(79)80144-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reactions of atoms with HCOND2, CH3ND2 and CH2OD have been studied by arrested relaxation infrared chemiluminescence. The emission spectra of both the HF and DF products of each reaction measured. The resulting product vibrational energy distributions were different for reaction at the C, N or OD bonds. It is suggested that the origins of these differences lie in the dynamics of the attractive interactions exprinced by the F atom during the reaction. © 1979.
引用
收藏
页码:201 / 208
页数:8
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