DYNAMICS OF HYDROGEN ABSTRACTION FROM POLYATOMIC-MOLECULES BY FLUORINE-ATOMS

被引：33

作者：

MACDONALD, RG ^{[1
]}

SLOAN, JJ ^{[1
]}

WASSELL, PT ^{[1
]}

机构：

[1] NATL RES COUNCIL CANADA, DIV CHEM, OTTAWA K1A 0R6, ONTARIO, CANADA

来源：

CHEMICAL PHYSICS | 1979年 / 41卷 / 1-2期

关键词：

D O I：

10.1016/0301-0104(79)80144-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reactions of atoms with HCOND2, CH3ND2 and CH2OD have been studied by arrested relaxation infrared chemiluminescence. The emission spectra of both the HF and DF products of each reaction measured. The resulting product vibrational energy distributions were different for reaction at the C, N or OD bonds. It is suggested that the origins of these differences lie in the dynamics of the attractive interactions exprinced by the F atom during the reaction. © 1979.

引用

页码：201 / 208

页数：8

共 34 条

[1] REACTIONS OF MOLECULES IN DEFINED VIBRATIONAL-STATES (III) REACTION OF HCL(R) WITH HDCL AND BR ATOMS [J].

ARNOLDI, D ;

WOLFRUM, J .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1976, 80 (09) :892-902

[2] HF IR CHEMILUMINESCENCE - VIBRATIONAL AND ROTATIONAL ENERGY DISPOSAL FOR REACTIONS OF FLUORINE-ATOMS WITH FORMALDEHYDE, ACETALDEHYDE, BENZALDEHYDE, AND DIMETHYL ETHER [J].

BOGAN, DJ ;

SETSER, DW ;

SUNG, JP .

JOURNAL OF PHYSICAL CHEMISTRY, 1977, 81 (09) :888-898

[3] HF INFRARED CHEMILUMINESCENCE - ENERGY DISPOSAL AND ROLE OF RADICAL FRAGMENT IN ABSTRACTION OF HYDROGEN FROM POLYATOMIC-MOLECULES BY F ATOMS [J].

BOGAN, DJ ;

SETSER, DW .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (02) :586-602

[4] ENERGY-DISTRIBUTION AMONG REACTION-PRODUCTS .11. H + CLF-]HF + CL, HCL + F [J].

BRANDT, D ;

POLANYI, JC .

CHEMICAL PHYSICS, 1978, 35 (1-2) :23-34

[5]

CRUICKSHANK FR, 1963, J PHYS CHEM-US, V13, P733

[6]

DING AMG, 1973, FARADAY DISCUSS, P252

[7] EFFECT OF CHANGING REAGENT ENERGY ON REACTION DYNAMICS .6. DEPENDENCE OF REACTION-RATE ON VIBRATIONAL-EXCITATION IN SUBSTANTIALLY ENDOTHERMIC REACTIONS, XH(UPSILON')+Y-]X+HY [J].

DOUGLAS, DJ ;

POLANYI, JC ;

SLOAN, JJ .

CHEMICAL PHYSICS, 1976, 13 (01) :15-31

[8] EFFECT OF REAGENT VIBRATIONAL-EXCITATION ON RATE OF A SUBSTANTIALLY ENDOTHERMIC REACTION - HCL(UPSILON'=1-4)+BR-]CL+HBR [J].

DOUGLAS, DJ ;

POLANYI, JC ;

SLOAN, JJ .

JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (12) :6679-6680

[9] INFRARED CHEMILUMINESCENCE STUDIES OF CHLORINE SUBSTITUTION-REACTIONS WITH BROMINATED UNSATURATED-HYDROCARBONS [J].

DURANA, JF ;

MCDONALD, JD .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (06) :2518-2527

[10] QUESTION OF ENERGY RANDOMIZATION IN DECOMPOSITION OF CHEMICALLY ACTIVATED C-2H-4F [J].

FARRAR, JM ;

LEE, YT .

JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (04) :1414-1426

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