MOLECULAR TUBE MODELS OF BRANCHED POLYMER MELTS

被引:5
作者
MCLEISH, TCB
OCONNOR, KP
机构
[1] Department of Physics, University of Sheffield, Sheffield, S10 2un, Hounsfield Road
来源
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1992年 / 56卷
关键词
D O I
10.1002/masy.19920560114
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We apply the tube model to a specific problem in polymer melt dynamics - the rheology of star polymers as an additive to a monodisperse linear matrix. We find that the tube dilation picture of constraint release may be applied to the relaxation of the star fraction. There are four qualitatively different cases depending on the relative concentrations and relaxation times of the two fractions. Terminal relaxation times and relaxation spectra are calculated for each case and compared with available experimental data. The existence of a modified Rouse relaxation such that G(t) approximately t-3/2 is argued.
引用
收藏
页码:127 / 134
页数:8
相关论文
共 15 条
[1]   DYNAMIC DILUTION AND THE VISCOSITY OF STAR POLYMER MELTS [J].
BALL, RC ;
MCLEISH, TCB .
MACROMOLECULES, 1989, 22 (04) :1911-1913
[2]  
COLBY RH, 1991, IN PRESS MACROMOLECU
[3]   REPTATION OF STARS [J].
DEGENNES, PG .
JOURNAL DE PHYSIQUE, 1975, 36 (12) :1199-1203
[4]  
DOI M, 1987, MACROMOLECULES, V20, P1900, DOI 10.1021/ma00174a035
[5]  
DOI M, 1980, J POLYM SCI POL LETT, V18, P775, DOI 10.1002/pol.1980.130181205
[6]  
Doi M., 1988, THEORY POLYM DYNAMIC
[8]   MOLECULAR RHEOLOGY OF H-POLYMERS [J].
MCLEISH, TCB .
MACROMOLECULES, 1988, 21 (04) :1062-1070
[9]   HIERARCHICAL-RELAXATION IN TUBE MODELS OF BRANCHED POLYMERS [J].
MCLEISH, TCB .
EUROPHYSICS LETTERS, 1988, 6 (06) :511-516
[10]   VISCOELASTIC PROPERTIES OF STAR-SHAPED POLYMERS [J].
PEARSON, DS ;
HELFAND, E .
MACROMOLECULES, 1984, 17 (04) :888-895