ELECTROCHEMICAL POLYMERIZATION OF ACRYLONITRILE WITH QUATERNARY-SALTS

被引：23

作者：

BHADANI, SN

ANSARI, Q

GUPTA, SKS

机构：

[1] Department of Chemistry, Ranchi University, Ranchi

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1992年 / 44卷 / 01期

关键词：

801 Chemistry - 802 Chemical Apparatus and Plants; Unit Operations; Unit Processes - 804 Chemical Products Generally - 815 Polymers and Polymer Science - 817 Plastics and Other Polymers: Products and Applications;

D O I：

10.1002/app.1992.070440112

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The electrochemical polymerization of acrylonitrile was carried out in the solutions of tetrabutylammonium bromide and tetrabutylphosphonium bromide in N,N-dimethylformamide in a divided electrolytic cell. The formation of polyacrylonitrile of high molecular weight (7.6 X 10(4)) took place in the cathode compartment. The kinetics of the polymerization was investigated for different initial monomer concentrations, current levels, and electrode materials. The polymerization mechanism is anionic.

引用

页码：121 / 126

页数：6

共 11 条

[1]

ASAHARA T, 1969, KINZOKII HYOMEN GIJU, V20, P64

[2]

BAIZER MN, 1966, Patent No. 3245889

[3] SOME MATHEMATICAL FORMULATIONS OF ELECTROCHEMICAL POLYMERIZATION KINETICS [J].