CALCULATION OF ACTIVATION-ENERGY AND PREEXPONENTIAL FACTORS FROM RISING TEMPERATURE DATA AND THE GENERATION OF TG AND DTG CURVES FROM A-VALUES AND E-VALUES

被引:45
作者
DOLLIMORE, D
EVANS, TA
LEE, YF
WILBURN, FW
机构
[1] Department of Chemistry, University of Toledo, Toledo
关键词
D O I
10.1016/0040-6031(91)80206-X
中图分类号
O414.1 [热力学];
学科分类号
摘要
After reviewing present methods of evaluating E, the activation energy, and A, the pre-exponential constant, and pointing out some of the inherent weaknesses of the method, a technique is outlined whereby a DTG and/or TG curve may be produced for direct comparison with experimental curves by assuming values for A and E and using finite difference techniques to produce such a curve.
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页码:77 / 85
页数:9
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