RUTHENIUM CLUSTERS WITH NITROGEN LIGANDS .4. DOUBLE C-H ACTIVATION OF KETIMINE METHYL-GROUPS ON TRIRUTHENIUM CARBONYL CLUSTERS - CRYSTAL-STRUCTURE OF RU3(MU-H)(2)[MU(3)-ETA(2)-(N,C)-4-HOC6H4N=CMECH](CO)(9) - ET(2)O

被引：5

作者：

CIFUENTES, MP

JEYNES, TP

GRAY, M

HUMPHREY, MG

SKELTON, BW

WHITE, AH

机构：

[1] UNIV NEW ENGLAND, DEPT CHEM, ARMIDALE, NSW 2351, AUSTRALIA

[2] UNIV WESTERN AUSTRALIA, DEPT CHEM, NEDLANDS, WA 6907, AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 494卷 / 1-2期

基金：

澳大利亚研究理事会;

关键词：

RUTHENIUM; CARBONYL; KETOIMINE; CRYSTAL STRUCTURE; FLUXIONALITY;

D O I：

10.1016/0022-328X(95)05416-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Ru-3(CO)(12) with the Schiff base 4-hydroxyphenyl-N,N-dimethylimide in refluxing cyclohexane gave the title complex in excellent yield. An X-ray crystallographic study showed that the product is derived from an unusual double C-H activation of the methyl group. An analogous reaction with the asymmetric Schiff base p-hydroxyphenyl-N,N-isobutylmethylimide showed that this reaction is specific for the imine-bound methyl group.

引用

页码：267 / 272

页数：6

共 14 条

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