HYDROGEN-BONDING IN FERROCENE DERIVATIVES - CRYSTAL-STRUCTURE OF RACEMIC FERROCENYL(PHENYL)METHANOL

被引：25

作者：

FERGUSON, G

GALLAGHER, JF

GLIDEWELL, C

ZAKARIA, CM

机构：

[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

[2] UNIV GUELPH,DEPT CHEM & BIOCHEM,GUELPH N1G 2W1,ON,CANADA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 01期

关键词：

FERROCENE; HYDROGEN BONDING; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)87015-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A single-crystal X-ray diffraction study has been carried out on racemic ferrocenyl(phenyl)methanol. There are two independent chiral molecules A and B in the asymmetric unit, and the molecules are linked by OH...O hydrogen bonds into zigzag chains characterized by the motif -S(A)-R(B)-R(A)-S(B)-; within these chains the two independent hydrogen-bonded O...O distances are 3.059(2) and 3.150(2) Angstrom.

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页码：95 / 101

页数：7

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