TRANSITION-METAL PNICTIDE SYNTHESIS - SELF-PROPAGATING REACTIONS INVOLVING SODIUM ARSENIDE, ANTIMONIDE AND BISMUTHIDE

被引：16

作者：

HECTOR, AL

PARKIN, IP

机构：

[1] UCL, CHRISTOPHER INGOLD LABS, DEPT CHEM, LONDON WC1H 0AJ, ENGLAND

[2] OPEN UNIV, DEPT CHEM, MILTON KEYNES MK7 6AA, BUCKS, ENGLAND

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1994年 / 49卷 / 04期

关键词：

METAL ARSENIDE; SODIUM ARSENIDE; METAL ANTIMONIDE; SODIUM ANTIMONIDE; SOLID STATE METATHESIS;

D O I：

10.1515/znb-1994-0408

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Initiation of the reaction between Na(3)E (E = As, Sb, Bi) and anhydrous metal halides at 25 to 550 degrees C produces metal arsenides M(x)As(y) (M = Y, La, Ti, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Pt, Cu and Zn) and antimonides M(x)Sb(y) (M = Ti, V, Nb, Ta, Cr, Fe, Co, Ni, Pt, Cu and Zn) via an exothermic selfpropagating reaction. The metal arsenides were characterized by X-ray powder diffraction, SEM/EDAX, microanalysis and FT-IR.

引用

页码：477 / 482

页数：6

共 20 条

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