CHEMISTRY OF ALLENE .4. CATALYZED CYCLODIMERIZATION OF ALLENE AND A NEW ALLENE PENTAMER

被引：33

作者：

HOOVER, FW

LINDSEY, RV

机构：

[1] Central Research Department, Experimental Station, E. I. du Pont de Nemours and Company, Wilmington

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 10期

关键词：

D O I：

10.1021/jo01262a057

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allene undergoes cyclodimerization to 1,3- and 1,2-dimethylenecyclobutane in the vapor phase over phosphine-modified nickel carbonyls. A polymeric complex of composition [p-(C6H5)2PC6H4P(C6H5)2.Ni(CO)2]x is a particularly effective catalyst. This same complex catalyzes the cyclomerization of allene in the liquid phase to a tetramer, a pentamer, and higher oligomers. © 1969, American Chemical Society. All rights reserved.

引用

页码：3051 / &

共 9 条

[1] CHEMISTRY OF ALLENE .1. CYCLOPOLYMERIZATION - SYNTHESIS AND CHEMISTRY OF 1,2,4-TRIMETHYLENECYCLOHEXANE AND 1,3,5-TRIMETHYLENECYCLOHEXANE AND 1,3,5,7-TETRAMETHYLENECYCLOOCTANE
BENSON, RE
LINDSEY, RV
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (16) : 4247 - 4250
[2] CATALYSED COPE REARRANGEMENT OF CIS-1,2-DIVINYLCYCLOBUTANE
HEIMBACH, P
BRENNER, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1967, 6 (09) : 800 - &
[3] REACTIONS OF 1,4-BIS(DIPHENYLPHOSPHINO)BENZENEWITH PHENYL AZIDE AND 1,4-DIAZIDOBENZENE
HERRING, DL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (10) : 3998 - &
[4] CHEMISTRY OF ALLENE .3. CYCLOOLIGOMERIZATION . SYNTHESIS OF 1,4,7-TRIMETHYLENESPIRO[4.4]NONANE AND A NEW PENTAMER
JONES, FN
LINDSEY, RV
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (10) : 3838 - +
[5] PREPARATION OF TETRACYCLO[4.3.0.02,4.03,7' NON-8-ENE AND DIMERIZATION OF IT AND OF BENZONORBORNADIENE BY RHODIUM ON CARBON
KATZ, TJ
CARNAHAN, JC
BOECKE, R
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (05) : 1301 - &
[6] OTSUKA S, 1969, TETRAHEDRON LETT, P297
[7] SCHRAUZER GN, 1968, ADVAN CATAL, V18, P377
[8] OLIGOMERS OF ALLENE .3. TETRAMERS FORMED IN THERMAL POLYMERIZATION OF LIQUID ALLENE
WEINSTEIN, B
FENSELAU, AH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (07) : 2278 - +
[9] OLIGOMERS OF ALLENE .2. DIMERS AND TRIMERS FORMED IN THERMAL POLYMERISATION OF LIQUID ALLENE
WEINSTEIN, B
FENSELAU, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (05): : 368 - +

← 1 →