EXPLANATION OF ANOMALOUS RESULTS IN THE NMR RELAXATION OF A PROBE IN LIQUID-CRYSTALLINE MEDIA

被引:5
作者
LOPESCARDOZO, HA [1 ]
BULTHUIS, J [1 ]
FREED, JH [1 ]
BOVEE, WMMJ [1 ]
机构
[1] DELFT UNIV TECHNOL,DEPT APPL PHYS,DELFT,NETHERLANDS
基金
美国国家科学基金会;
关键词
D O I
10.1016/0009-2614(79)80048-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The methyl-13C and the 14N longitudinal relaxation times in acetonitrile, dissolved in a thermotropic liquid crystal are analyzed with a slowly relaxing local structure model. This model gives rise to a frequency dependent relaxation mechanism which explains the relatively short 14N relaxation time compared to the methyl-13C relaxation time. © 1979.
引用
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页码:335 / 337
页数:3
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