ON THE STEREOCHEMICAL CONTROL OF COMPLEXATION IN TETRAHYDROPYRANOID PODAND IONOPHORES

被引：33

作者：

ERICKSON, SD

STILL, WC

机构：

[1] Department of Chemistry, Columbia University, New York

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 30期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)97593-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

To test a proposal that stereochemistry can be used rationally to control the binding properties of ionophores, a new podand (3) has been prepared and studied. Unlike the previously prepared stereoisomeric podand 2 which has substitution and stereochemistry which enforces a single tetradentate binding conformation, 3 has been designed to avoid conformations in which all four oxygens can simultaneously coordinate with an ion. © 1990.

引用

页码：4253 / 4256

页数：4

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