CYCLOPROPYLCARBINYL PENTAMETHYLBENZENESULFONATE SOLVOLYSIS - STUDY OF RESPONSE TO SOLVENT IONIZING STRENGTH

被引：12

作者：

ROBERTS, DD

SNYDER, RC

机构：

[1] Department of Chemistry, Louisiana Tech University, Ruston, Louisiana

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 16期

关键词：

D O I：

10.1021/jo01330a009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The solvolysis rates of cyclopropylcarbinyl pentamethylbenzenesulfonate (3-OPms) have been determined in a series of aqueous alcohol and carboxylic acid solvents. The kinetic data indicate that 3-OPms ionizes via the κΔ pathway and that neighboring-group assistance by the cyclopropane ring is characterized by a different response to solvent ionizing strength than that by an aryl group. © 1979, American Chemical Society. All rights reserved.

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页码：2860 / 2863

页数：4

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