A 2ND CRYSTAL MODIFICATION OF BIS[2,4,6-TRIS(TRIFLUOROMETHYL)PHENYL]STANNYLENE - A STANNYLENE (STANNANEDIYL) DIMER WITH WEAK TIN TIN INTERACTIONS

被引：73

作者：

LAY, U ^{[1
]}

PRITZKOW, H ^{[1
]}

GRUTZMACHER, H ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,NEUENHEIMER FELD 270,W-6900 HEIDELBERG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000260

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In a second crystal modification 4' the stannylene [2,3,5-(CF3)3C6H2]2Sn forms a weakly associated dimer with a long tin-tin distance of 3.639(1) angstrom; this structure is compared with the known dimeric structures of the species [(PhCH2)5C5In]2 5, [(PhCH2)5C5Tl]2 6 and 2,2',5,5'-tetramethylbistibole 7 with an s2 electronic configuration.

引用

页码：260 / 262

页数：3

共 33 条

[1] 2,2',5,5'-TETRAMETHYLDISTIBOLYL - A THERMOCHROMIC DISTIBINE [J].

ASHE, AJ ;

BUTLER, W ;

DIEPHOUSE, TR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (01) :207-209

[2] MOLECULAR AND CRYSTAL-STRUCTURE OF 2,2',5,5'-TETRAMETHYL-1,1'-DISTIBAFERROCENE - A SHORT SB=SB INTER-RING CONTACT [J].

ASHE, AJ ;

DIEPHOUSE, TR ;

KAMPF, JW ;

ALTAWEEL, SM .

ORGANOMETALLICS, 1991, 10 (06) :2068-2071

[3]

BUDZELAAR PHM, 1990, RECL TRAV CHIM PAY B, V109, P187

[4] POTENTIALLY CONDUCTING ORGANOMETALLIC SYSTEMS - THE STIBAPHENALENYL SERIES [J].

CANADELL, E ;

SHAIK, SS .

INORGANIC CHEMISTRY, 1987, 26 (22) :3797-3802

[5] SUB-VALENT GROUP 4B METAL ALKYLS AND AMIDES .2. CHEMISTRY AND PROPERTIES OF BIS[BIS(TRIMETHYLSILYL)METHYL]TIN (II) AND ITS LEAD ANALOG [J].

COTTON, JD ;

DAVIDSON, PJ ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (21) :2275-2286

[6]

DAVIDSON PJ, 1974, J CHEM SOC CHEM COMM, P895

[7] PBMO5O8 AND TL0.8SN0.6MO7O11, NOVEL CLUSTERS OF MOLYBDENUM AND THALLIUM [J].

DRONSKOWSKI, R ;

SIMON, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (06) :758-760

[8]

Dronskowski R., 1989, ANGEW CHEM, V101, P775

[9] SUBVALENT GROUP-4B METAL ALKYLS AND AMIDES .9. GERMANIUM AND TIN ALKENE ANALOGS, THE DIMETALLENES M2R4 [M = GE OR SN, R = CH(SIME3)2] - X-RAY STRUCTURES, MOLECULAR-ORBITAL CALCULATIONS FOR M2H4, AND TRENDS IN THE SERIES M2R'4 [M = C, SI, GE, OR SN - R' = R, PH, C6H2ME3-2,4,6, OR C6H3ET2-2,6] [J].

GOLDBERG, DE ;

HITCHCOCK, PB ;

LAPPERT, MF ;

THOMAS, KM ;

THORNE, AJ ;

FJELDBERG, T ;

HAALAND, A ;

SCHILLING, BER .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (11) :2387-2394

[10]

GRUTZMACHER H, 1991, ORGANOMETALLICS, V10, P23

← 1 2 3 4 →