THERMOGRAVIMETRY FOURIER-TRANSFORM INFRARED COUPLING INVESTIGATIONS TO STUDY THE THERMAL-STABILITY OF MELAMINE-FORMALDEHYDE RESIN

被引:136
作者
DEVALLENCOURT, C
SAITER, JM
FAFET, A
UBRICH, E
机构
[1] FAC SCI MT ST AIGNAN,ETUD CARACTERISAT AMORPHES & POLYMERES LAB,F-76821 MONT ST AIGNAN,FRANCE
[2] INST FRANCAIS PETR,ANAL THERM LAB,F-92506 RUEIL MALMAISON,FRANCE
关键词
ENVIRONMENT APPLICATION; MELAMINE FORMALDEHYDE RESIN; TG/FTIR COUPLING ANALYSIS;
D O I
10.1016/0040-6031(95)02262-Z
中图分类号
O414.1 [热力学];
学科分类号
摘要
This work reports new results obtained for a stable melamine formaldehyde resin intermediate. Using thermogravimetry/Fourier transform infrared (TG/FTIR) coupling, qualitative and quantitative analyses of the effluents which appear during a thermal cycle were performed. Four successive mass losses appear on the thermogravimetric curve (between 40 and 145 degrees C, 145 and 225 degrees C, 225 and 440 degrees C, and for T > 440 degrees C). The TG/FTIR coupling analysis identifies most of the effluents (water, methanol, formaldehyde, CO2, amino compounds, ammonia).
引用
收藏
页码:143 / 151
页数:9
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