ELIMINATION OF BETA-PALLADIUM HYDROXIDE IN THE PD(II)-CATALYZED REACTION OF METHYL (ALPHA-HYDROXYMETHYL)ACRYLATE WITH ALCOHOLS

被引：19

作者：

HOSOKAWA, T

SUGAFUJI, T

YAMANAKA, T

MURAHASHI, S

机构：

[1] Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka, 560, Machikaneyama

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 470卷 / 1-2期

关键词：

PALLADIUM; HYDROXIDE; CATALYSIS; ALKENE; MECHANISM;

D O I：

10.1016/0022-328X(94)80175-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Exclusive elimination of beta-Pd-OH takes place in the oxypalladation intermediate derived from methyl (a-hydroxymethyl)acrylate and alcohols with PdCl2 catalyst, and no beta-Pd-H elimination occurs.

引用

页码：253 / 255

页数：3

共 17 条

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