SYNTHESIS AND REACTIONS OF DI-HYDROBENZ[B]INDOLIZINES AND TETRA-HYDROBENZ[B]INDOLIZINES

被引：4

作者：

TEITEI, T

DALTON, LK

机构：

[1] Division of Applied Chemistry, CSIRO Chemical Research Laboratories, Melbourne, VIC, 3001

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 05期

关键词：

D O I：

10.1071/CH9690997

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of 1-(4′,4′-diethoxybutyl)-3-methoxycarbonylindole with ethanolic hydrogen chloride gives in high yield 9-chloro-10-methoxycarbonyl-6,7,8,9-tetra-hydrobenz[b]indolizine which is readily converted into the 6,7-dihydro compound and the fully aromatic 10-methoxycarbonylbenz [b] indolizine. Substitution and addition reactions of these compounds have been studied. A mechanism for the formation of the chlorotetrahydrobenz[b]indolizines is discussed. © 1969, CSIRO. All rights reserved.

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页码：997 / &

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