ORGANIC SULFUR CHEMISTRY .59. A PRACTICAL, ONE-STEP SYNTHESIS OF PRIMARY THIOLS UNDER MILD AND NEUTRAL CONDITIONS USING BIS(TRIORGANOTIN) SULFIDES

被引：13

作者：

GINGRAS, M ^{[1
]}

HARPP, DN ^{[1
]}

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL H3A 2K6,QUEBEC,CANADA

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(00)88815-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thiols are obtained from primary organic halides and bis(triaryl/alkyltin) sulfides in the presence of fluoride ion in CH3CN/H2O at 20°C. This simple one-step methodology involving fluorodestannylation is carried out under mild and neutral conditions, in sharp contrast to virtually all known methods. Some attempts at utilizing triorganotin and triorganogermanium mercaptans for the same purpose are reported. © 1990.

引用

页码：1397 / 1400

页数：4

共 22 条

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