[ET]3[NICL4].H2O - A METALLIC CONDUCTOR CONTAINING THE NICL42- ANION IN A DISTORTED SQUARE-PLANAR GEOMETRY [ET = BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE]

被引：9

作者：

FITZMAURICE, JC ^{[1
]}

SLAWIN, AMZ ^{[1
]}

WILLIAMS, DJ ^{[1
]}

WOOLLINS, JD ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 19期

关键词：

D O I：

10.1039/c39930001479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound is a metallic conductor at room temperature and its crystal structure reveals that the NiCl42- anions are not tetrahedral but have a unusual distorted square planar geometry not previously reported; the NiCl42- anions are sandwiched between lamelli of ET cations.

引用

页码：1479 / 1480

页数：2

共 4 条

[1] LINEAR-CHAIN METAL-COMPOUNDS - [M(MNT)(CNME)2][M = NI, PD, PT MNT = 1,2-S2C2(CN)2] [J].

CONNELLY, NG ;

CROSSLEY, JG ;

ORPEN, AG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (21) :1568-1571

[2]

MARTIN J, UNPUB

[3] RATIONAL DESIGN OF SYNTHETIC METAL SUPERCONDUCTORS [J].

WILLIAMS, JM ;

WANG, HH ;

EMGE, TJ ;

GEISER, U ;

BENO, MA ;

LEUNG, PCW ;

CARLSON, KD ;

THORN, RJ ;

SCHULTZ, AJ ;

WHANGBO, MH .

PROGRESS IN INORGANIC CHEMISTRY, 1987, 35 :51-218

[4]

CSSR DATABASE CRYSTA

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