NAFION-SUPPORTED METAL-COMPLEXES - A RESONANCE RAMAN AND UV-VISIBLE SPECTROSCOPIC STUDY

被引：9

作者：

MACLEAN, AL ^{[1
]}

ARMSTRONG, RS ^{[1
]}

KENNEDY, BJ ^{[1
]}

机构：

[1] UNIV SYDNEY, SCH CHEM, SYDNEY, NSW 2006, AUSTRALIA

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 1993年 / 24卷 / 12期

关键词：

D O I：

10.1002/jrs.1250241212

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Resonance Raman and UV-visible spectra of cobalt tetraphenylporphyrin and cobalt phthalocyanine in Nafion were recorded. The spectroscopic measurements show that the porphyrin is incorporated into the hydrophobic regions of the polymer whilst the phthalocyanine is associated with the ionic domains. The macrocycles undergo a change in geometry in Nafion, the porphyrins exhibiting a decreased core size in the membrane.

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页码：897 / 901

页数：5

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