STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION OF 1,3-BIS-(4-METHYLPHENYL)IMIDAZOLIUM CHLORIDE

被引：16

作者：

FULLER, J

CARLIN, RT

机构：

[1] Frank J. Seiler Research Laboratory, USAF Academy, 80840-6272, Colorado, 2354 Vandenberg Drive

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1994年 / 24卷 / 08期

关键词：

IMIDAZOLIUM; CARBENES; SODIUM HYDRIDE;

D O I：

10.1007/BF01666725

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of 1,3-bis(4-methylphenyl) imidazolium chloride was determined and compared to its related imidazole-based carbene. The important structural difference is the greater N2-C2-N3 angle in the salt (109.6 degrees) than in the carbene (101.2 degrees). An electrochemical investigation of the salt revealed a single reduction at -2.32 V in the forward scan and two oxidations at -0.89 and -0.54 V following scan reversal.

引用

页码：489 / 493

页数：5

共 10 条

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