2-AMINO-1,3,2-DIOXABOROLANES AND THEIR PROPERTIES

被引：8

作者：

CRAGG, RH

机构：

[1] The Chemical Laboratory, University of Kent at Canterbury

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1968年 / 30卷 / 02期

关键词：

D O I：

10.1016/0022-1902(68)80465-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and properties of some 2-amino-1,3,2-dioxaborolanes, {A figure is presented} (R = R′ = Me; R = H and R′ = Me, Et, Pr′, Bun, Bui, But and Ph) are described and their association is discussed. Reaction of phenyl isocyanate with 2-dimethylamino-1,3,2-dioxaborolane is exocyclic showing that the relative migratory aptitude is R2N > OR. © 1968.

引用

收藏

页码：395 / &

相关论文

共 9 条

[1]

ABEL EW, 1957, J CHEM SOC, P4116

[2] INFRARED SPECTRA OF ETHYLENE AND ORTHO-PHENYLENE DERIVATIVES OF BORIC ACID [J].

BLAU, JA ;

GERRARD, W ;

LAPPERT, MF ;

MOUNTFIELD, BA ;

PYSZORA, H .

JOURNAL OF THE CHEMICAL SOCIETY, 1960, (JAN) :380-384

[3]

BROTHERTON RJ, 1960, J ORG CHEM, V26, P1668

[4] CHLOROBORATION + ALLIED REACTIONS OF UNSATURATED COMPOUNDS .3. AMINOBORATION + ALKOXYBORATION OF ISOCYANATES + ISOTHIOCYANATES [J].

CRAGG, RH ;

LAPPERT, MF ;

TILLEY, BP .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JUN) :2108-&

[5] REDUCTION OF SYMMETRICAL 1,2- AND 1,3-DIKETONES WITH SODIUM BOROHYDRIDE, AND SEPARATION OF DIASTEREOISOMERIC 1,2- AND 1,3-DIOLS BY MEANS OF BORATE COMPLEXES [J].

DALE, J .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (MAR) :910-&

[6] STEREOCHEMISTRY OF POLYBORATE ANIONS AND OF BORATE COMPLEXES OF DIOLS AND CERTAIN POLYOLS [J].

DALE, J .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (MAR) :922-&

[7]

DALE J, 1961, J CHEM SOC, P931

[8] ASSOCIATION IN CYCLIC BORONATES AND BORATES [J].

FINCH, A ;

GARDNER, PJ .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1963, 25 (08) :927-932

[9] CYCLIC BORON COMPOUNDS .8. AMINO- AND HYDRAZINO-BORANES AND THEIR CYCLIC DIMERS [J].

LAPPERT, MF ;

MAJUMDAR, MK ;

TILLEY, BP .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (11) :1590-&