HYDROGENATION OF PROPYLENE OVER GROUP 8 METALS

被引：28

作者：

MANN, RS

LIEN, TR

机构：

[1] Now at Department of Chemical Engineering, University of Toronto, Toronto, Ont.

[2] Department of Chemical Engineering, University of Ottawa, Ottawa

来源：

JOURNAL OF CATALYSIS | 1969年 / 15卷 / 01期

关键词：

D O I：

10.1016/0021-9517(69)90002-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction between propylene and hydrogen over pumice-supported metals of the eighth group has been investigated in a constant volume reactor for a wide range of temperature and reactant ratios. The orders of hydrogenation reaction are first, or slightly lower, and zero or slightly negative with respect to hydrogen and propylene respectively. The apparent activation energies for Ni, Fe, Co, Pt, Pd, Rh, Ir, Ru, and Os are 13.0, 10.0, 8.1, 16.0, 11.0, 13.0, 15.0, 6.5, and 7.4 kcal/mole respectively. The catalytic activity of the metals are in the sequence: Rh > Ir > Ru > Pt > Pd > Ni > Fe > Co > Os. © 1969.

引用

页码：1 / &

共 24 条

[1] CARBONYL NICKEL FILMS AS HYDROGENATION CATALYSTS [J].