INVESTIGATION OF THE OXIDATIVE CLEAVAGE OF BUTYL RUBBER BY SELECTIVE CATALYSIS

被引：19

作者：

GUIZARD, C

CHERADAME, H

机构：

[1] Laboratoire de chimie des polymères, Ecole Francaise de Papeterie, 38000 Grenoble, 44, avenue Félix Viallet

来源：

EUROPEAN POLYMER JOURNAL | 1979年 / 15卷 / 07期

关键词：

D O I：

10.1016/0014-3057(79)90097-1

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Selective oxidizing cleavage of carbon-carbon double bonds of unsaturated polymers leads to bifunctional oligomers. It is shown, using ruthenium tetroxide in catalytic amount in conjunction with a peracid as co-oxidizing agent, that efficient cleavage of butyl rubber double bonds can be obtained without side reaction. The procedure can be used for analytical as well as for synthetic purpose. © 1979.

引用

页码：689 / 693

页数：5

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