ELECTRON-PARAMAGNETIC RESONANCE OF MN2+ IONS IN ARAGONITE SINGLE-CRYSTALS

被引：10

作者：

SLEZAK, A ^{[1
]}

LECH, J ^{[1
]}

BOJKO, I ^{[1
]}

机构：

[1] PEDAGOG COLL,INST PHYS,OPOLE,POLAND

来源：

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH | 1979年 / 54卷 / 02期

关键词：

D O I：

10.1002/pssa.2210540242

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electron paramagnetic resonance at X‐band is studied in natural aragonite single crystals containing about 100 ppm Mn impurities. It is found that there are two inequivalent Mn2+ sites in the aragonite lattice. The principal axes Y of both the sites coincide. They are in <100> crystallographic directions. The principal axes XI, ZI, XII, ZII lie in the (b, c) crystal plane. The axes ZI and ZII are related at angles 65°. The crystallographic <001> direction bisects this angle. The EPR spectra of both these sites are well described with the same orthorhombic spin‐Hamiltonian parameters. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA

引用

页码：755 / 759

页数：5

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