NEW SUPERCONDUCTING SODIUM-NITROGEN-C60 TERNARY COMPOUND

被引：24

作者：

IMAEDA, K

KHAIRULLIN, II

YAKUSHI, K

NAGATA, M

MIZUTANI, N

KITAGAWA, H

INOKUCHI, H

机构：

[1] Institute for Molecular Science, Okazaki, 444, Myodaiji

来源：

SOLID STATE COMMUNICATIONS | 1993年 / 87卷 / 05期

关键词：

D O I：

10.1016/0038-1098(93)90780-Q

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We have prepared sodium-doped C60 utilizing the thermal decomposition of sodium azide (NaN3). The strong low-Magnetic field microwave absorption with a clear hysteresis was observed in the samples of NanC60 (n=3-4), indicating the superconducting nature. By means of a SQUID measurement, the superconducting transition temperature is found to be around 12 K. Significantly, elemental analysis detected a nitrogen which was surely produced in the process of die thermal decomposition of NaN3. We suppose that this new superconducting phase will be NaxNyC60 where x is between 3 and 4, and y is unknown. This is the first superconducting material in Na-doped C60 without other alkali metals.

引用

收藏

页码：375 / 378

页数：4

相关论文

共 9 条

[1] A NEW PREPARATION METHOD FOR SUPERCONDUCTING ALKALI-METAL-DOPED FULLERENES - COMPARISON OF AC SUSCEPTIBILITY AND LOW-FIELD MICROWAVE-ABSORPTION CHARACTERIZATION [J].

BENSEBAA, F ;

XIANG, BS ;

KEVAN, L .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (15) :6118-6120

[2] SYNTHESIS AND CHARACTERIZATION OF ALKALI-METAL FULLERIDES - AXC60 [J].

MURPHY, DW ;

ROSSEINSKY, MJ ;

FLEMING, RM ;

TYCKO, R ;

RAMIREZ, AP ;

HADDON, RC ;

SIEGRIST, T ;

DABBAGH, G ;

TULLY, JC ;

WALSTEDT, RE .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1992, 53 (11) :1321-1332

[3] STRUCTURAL AND ELECTRONIC-PROPERTIES OF SODIUM-INTERCALATED C-60 [J].

ROSSEINSKY, MJ ;

MURPHY, DW ;

FLEMING, RM ;

TYCKO, R ;

RAMIREZ, AP ;

SIEGRIST, T ;

DABBAGH, G ;

BARRETT, SE .

NATURE, 1992, 356 (6368) :416-418

[4] STRUCTURE OF SINGLE-PHASE SUPERCONDUCTING K3C60 [J].

STEPHENS, PW ;

MIHALY, L ;

LEE, PL ;

WHETTEN, RL ;

HUANG, SM ;

KANER, R ;

DEIDERICH, F ;

HOLCZER, K .

NATURE, 1991, 351 (6328) :632-634

[5] SUPERCONDUCTIVITY IN SODIUM-CONTAINING AND LITHIUM-CONTAINING ALKALI-METAL FULLERIDES [J].

TANIGAKI, K ;

HIROSAWA, I ;

EBBESEN, TW ;

MIZUKI, J ;

SHIMAKAWA, Y ;

KUBO, Y ;

TSAI, JS ;

KUROSHIMA, S .

NATURE, 1992, 356 (6368) :419-421

[6] INTERCALATION OF SODIUM HETEROCLUSTERS INTO THE C-60 LATTICE [J].

YILDIRIM, T ;

ZHOU, O ;

FISCHER, JE ;

BYKOVETZ, N ;

STRONGIN, RA ;

CICHY, MA ;

SMITH, AB ;

LIN, CL ;

JELINEK, R .

NATURE, 1992, 360 (6404) :568-571

[7] EVOLUTION OF SUPERCONDUCTIVITY OF KXC60 UPON K-DOPING - MICROWAVE LOW-FIELD SIGNAL AND ESR STUDY [J].

ZAKHIDOV, AA ;

UGAWA, A ;

IMAEDA, K ;

YAKUSHI, K ;

INOKUCHI, H ;

KIKUCHI, K ;

IKEMOTO, I ;

SUZUKI, S ;

ACHIBA, Y .

SOLID STATE COMMUNICATIONS, 1991, 79 (11) :939-946

[8]

ZAKHIDOV AA, 1992, MOL CRYST LIQUID CRY, V218, P299

[9] INCREASED TRANSITION-TEMPERATURE IN SUPERCONDUCTING NA2CSC60 BY INTERCALATION OF AMMONIA [J].

ZHOU, O ;

FLEMING, RM ;

MURPHY, DW ;

ROSSEINSKY, MJ ;

RAMIREZ, AP ;

VANDOVER, RB ;

HADDON, RC .

NATURE, 1993, 362 (6419) :433-435