OPTICAL-PROPERTIES OF POLYANILINE THIN-FILMS

被引：23

作者：

SCULLY, M ^{[1
]}

PETTY, MC ^{[1
]}

MONKMAN, AP ^{[1
]}

机构：

[1] UNIV DURHAM,DEPT PHYS,ORGAN ELECTROACT MAT RES GRP,DURHAM DH1 3LE,ENGLAND

来源：

SYNTHETIC METALS | 1993年 / 55卷 / 01期

关键词：

D O I：

10.1016/0379-6779(93)90930-U

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We report the preparation and properties of ultra-thin films of polyaniline formed by spinning. The polyaniline, dissolved in N-methyl-2-pyrrolidinone, was found to behave as a non-Newtonian fluid. However, high quality films could be produced under appropriate conditions. From these spun films of emeraldine base, we have calculated the absorption coefficient of both the benzenoid pi-pi* transition observed at 320nm and the quinoid ring absorption seen at 610nm, which leads to self-trapped exciton formation.

引用

页码：183 / 187

页数：5

共 14 条

[1] SPIN COATING - ONE-DIMENSIONAL MODEL
BORNSIDE, DE
MACOSKO, CW
SCRIVEN, LE
[J]. JOURNAL OF APPLIED PHYSICS, 1989, 66 (11) : 5185 - 5193
[2] BREDAS JL, 1992, P NOBEL S CONGUGATED, P9
[3] A MATHEMATICAL-MODEL FOR SPIN COATING OF POLYMER RESISTS
FLACK, WW
SOONG, DS
BELL, AT
HESS, DW
[J]. JOURNAL OF APPLIED PHYSICS, 1984, 56 (04) : 1199 - 1206
[4] FUJIMOTO H, 1985, SYNTHETIC METALS, V10
[5] HEAVENS OS, 1984, OPTICAL PROPERTIES T, P9
[6] Holland L., 1964, PROPERTIES GLASS SUR
[7] THE SHEAR VISCOSITY DEPENDENCE ON CONCENTRATION, MOLECULAR-WEIGHT, AND SHEAR RATE OF POLYSTYRENE SOLUTIONS
KULICKE, WM
KNIEWSKE, R
[J]. RHEOLOGICA ACTA, 1984, 23 (01) : 75 - 83
[8] LAWERENCE CJ, 1988, PHYS FLUIDS, V31, P2786
[9] OPTICAL AND ELECTRONIC-PROPERTIES OF STRETCH-ORIENTED SOLUTION-CAST POLYANILINE FILMS
MONKMAN, AP
ADAMS, P
[J]. SYNTHETIC METALS, 1991, 40 (01) : 87 - 96
[10] Mott N F, 1979, ELECTRONIC PROCESSES, P291

← 1 2 →