LUMINESCENCE AND INTERSYSTEM CROSSING IN FLUID SOLUTIONS OF CR(NH3)2(NCS)4-AND CR(NCS)63-

被引：28

作者：

KANG, YS ^{[1
]}

CASTELLI, F ^{[1
]}

FORSTER, LS ^{[1
]}

机构：

[1] UNIV ARIZONA,DEPT CHEM,TUCSON,AZ 85721

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 18期

关键词：

D O I：

10.1021/j100481a012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lifetimes and relative values of the intersystem crossing efficiencies have been determined for Cr(NH3)2(NCS)4- and Cr(NCS)63- in pure and mixed solvents. Intersystem crossing is independent of solvent, and it is suggested that the 4T2 and 2E states are both significantly photoreactive. © 1979 American Chemical Society.

引用

页码：2368 / 2371

页数：4

共 18 条

[1] QUENCHING AND SENSITIZATION PROCESSES OF COORDINATION-COMPOUNDS
BALZANI, V
MOGGI, L
MANFRIN, MF
BOLLETTA, F
[J]. COORDINATION CHEMISTRY REVIEWS, 1975, 15 (04) : 321 - 433
[2] RELAXATION OF EXCITED STATES IN CR(3) COMPLEXES
CAMASSEI, FD
FORSTER, LS
[J]. JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (06) : 2603 - &
[3] 4T2 STATE LIFETIMES AND INTERSYSTEM CROSSING EFFICIENCIES IN CHROMIUM(III) COMPLEXES
CASTELLI, F
FORSTER, LS
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1977, 81 (05) : 403 - 408
[4] The role of doublet and quartet states in the photoaquation of the reineckate ion
Chen, Schoen-Nan
Porter, Gerald E.
[J]. CHEMICAL PHYSICS LETTERS, 1970, 6 (01) : 41 - 42
[5] EXCITED-STATE RELAXATION AND CHROMIUM(III) PHOTOCHEMISTRY
CONTI, C
FORSTER, LS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (02) : 613 - 614
[6] PHOTOPHYSICS OF CR(CN)63- AND CO(CN)63- IN POLY-ALCOHOL-WATER SOLUTIONS AT ROOM-TEMPERATURE
CONTI, C
CASTELLI, F
FORSTER, LS
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (18) : 2371 - 2376
[7] MEDIUM EFFECTS ON TRANS-CR(NH3)2(NCS)4- PHOSPHORESCENCE
GUTIERREZ, AR
ADAMSON, AW
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1978, 82 (08) : 902 - 907
[8] EXCITED-STATES AND INTERMEDIATES IN PHOTOCHEMISTRY OF CHROMIUM(III) COMPLEXES STUDIED BY FLASH METHOD
OHNO, T
KATO, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1973, 46 (06) : 1602 - 1609
[9] QUENCHING OF PHOSPHORESCENCE OF SOME CHROMIUM(III) COMPLEXES BY MOLECULAR OXYGEN
PFEIL, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (21) : 5395 - &
[10] PICOSECOND STUDIES OF EXCITED-STATE DECAY KINETICS IN CHROMIUM(III) - TRANS-DIISOTHIOCYANATO-BIS(ETHYLENEDIAMINE)CHROMIUM(III), REINECKES SALT, AND HEXAISOTHIOCYANATOCHROMIUM(III) IN H2O AND D2O AT ROOM-TEMPERATURE
PYKE, SC
WINDSOR, MW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (20) : 6518 - 6519

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