SYNTHESIS OF FLUORINE-CONTAINING ORGANOSILICON OLIGOMERS

被引：64

作者：

SAWADA, H

NAKAYAMA, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 10期

关键词：

D O I：

10.1039/c39910000677

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New fluorine-containing organosilicon oligomers, R(F)(CH2CHSiR3)(x)R(F) {x = 2 or 3, R(F) = C3F7 or CF(CF3)[OCF2CF(CF3)]yOC3F7, y = 0 or 1; R = OMe or Me} were obtained by the reactions of fluoroalkanoyl peroxides with the corresponding vinylsilanes in excellent to moderate yields under very mild conditions.

引用

收藏

页码：677 / 678

页数：2

相关论文

共 15 条

[1]

ISHIKAWA N, 1971, KOG KAGAKU ZASSHI, V74, P1680

[2]

KADINA MA, 1967, ZH OBSHCH KHIM+, V37, P930

[3] ORGANIC FLUORINE SILICON-COMPOUNDS .12. PREPARATION OF (FLUOROARYL)METHYLDIETHOXYSILANES [J].

KURODA, K ;

ISHIKAWA, N .

NIPPON KAGAKU KAISHI, 1972, (10) :1876-&

[4]

KURODA K, 1971, KOGYO KAGAKU ZASSHI, V74, P2123

[5] SYNTHESES OF PERFLUORALKYLATED STYRENE MONOMERS WITH BIS(PERFLUOROALKANOYL) PEROXIDES [J].

MITANI, M ;

SAWADA, H ;

NAKAYAMA, M ;

YOSHIDA, M ;

KAMIGATA, N .

POLYMER JOURNAL, 1990, 22 (07) :623-627

[6] THE REACTIONS OF HYDROSILANES WITH TRIFLUOROPROPENE AND PENTAFLUOROSTYRENE CATALYZED BY RUTHENIUM, RHODIUM AND PALLADIUM COMPLEXES [J].

OJIMA, I ;

FUCHIKAMI, T ;

YATABE, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 260 (03) :335-346

[7] SYNTHESIS AND PROPERTY COMPARISONS OF RANDOM AND ALTERNATING HYBRID FLUOROCARBON-FLUOROSILICONE COPOLYMERS [J].

RILEY, MO ;

KIM, YK ;

PIERCE, OR .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1978, 16 (08) :1929-1941

[8] SYNTHESIS OF FLUOROETHER-FLUOROSILICONE HYBRID POLYMERS [J].

RILEY, MO ;

KIM, YK ;

PIERCE, OR .

JOURNAL OF FLUORINE CHEMISTRY, 1977, 10 (02) :85-110

[9]

ROSENBERG H, 1979, PREP ORG COATING PLA, V40, P792

[10] TRIFLUOROMETHYLATION OF AROMATIC-COMPOUNDS WITH BIS(TRIFLUOROACETYL) PEROXIDE [J].

SAWADA, H ;

NAKAYAMA, M ;

YOSHIDA, M ;

YOSHIDA, T ;

KAMIGATA, N .

JOURNAL OF FLUORINE CHEMISTRY, 1990, 46 (03) :423-431