AN N,N'-BIS(SALICYLIDENE)-1,3-PROPANEDIAMINE-NICKEL COMPLEX

被引：22

作者：

ELERMAN, Y ^{[1
]}

KABAK, M ^{[1
]}

ATAKOL, O ^{[1
]}

机构：

[1] UNIV ANKARA,FAC SCI,DEPT CHEM,ANKARA,TURKEY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193004615

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the crystal structure of this Ni-II complex with bis(salicylidene)-1,3-diaminopropane, aqua{2,2'-[1,3-propanediylbis(nitrilomethylidyne)]diphenolato}- nickel(II), nickel is five-coordinate with a water molecule at the apex of a square pyramid. The complex has symmetry m and the two Schiff base moieties, which in themselves are planar, are inclined at 38.6 (4)degrees to each other, forming a shallow umbrella form. The configuration at the N atoms is planar, as would be expected of sp(2) hybridization.

引用

页码：1905 / 1906

页数：2