PROPAGATION AND TERMINATION RATE CONSTANTS OF DIALKYL ITACONATES BEARING CYCLOHEXYL-BASED ESTER GROUPS IN RADICAL POLYMERIZATION

被引：16

作者：

MATSUMOTO, A

YAMAGISHI, K

OTSU, T

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka City University, Sumiyoshi-ku, Osaka, 558, Sugimoto

来源：

EUROPEAN POLYMER JOURNAL | 1995年 / 31卷 / 02期

关键词：

D O I：

10.1016/0014-3057(94)00145-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Radical polymerization of dialkyl itaconates bearing cyclohexyl-based ester alkyl groups was examined kinetically. The propagation and termination rate constants were determined during the polymerization with dimethyl 2,2'-azobisisobutyrate in benzene at 60 by electron spin resonance spectroscopy. It was confirmed that the large kinetic orders with respect to the monomer in these polymerizations were related to the variable termination rate constant depending on the monomer concentration.

引用

页码：121 / 124

页数：4

共 11 条

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