AN ELECTRON RESONANCE STUDY OF SOME PHOTOCHEMICALLY GENERATED FREE RADICALS

被引：68

作者：

HUDSON, A

HUSSAIN, HA

机构：

[1] Chemical Laboratory, University of Sussex, Brighton

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 07期

关键词：

D O I：

10.1039/j29690000793

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The abstraction of hydrogen atoms by photochemically generated t-butoxyl radicals can be used to produce steady-state concentrations of free radicals detectable by e.s.r. The hyperfine splitting constants of several new species have been measured and are discussed in terms of their probable structures. In particular, the technique provides a simple route to radicals containing heteroatoms such as Si, Ge, Sn, B, and P.

引用

页码：793 / &

共 36 条

[1] ELECTRON PARAMAGNETIC RESONANCE OF T-BUTOXY RADICAL REACTIONS WITH ALCOHOLS
ADAMS, JQ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (20) : 5363 - &
[2] ELECTRON SPIN RESONANCE STUDIES OF SILICON- AND GERMANIUM-SUBSTITUED ANION RADICALS
ALLRED, AL
BUSH, LW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (13) : 3352 - &
[3] ELECTRON SPIN RESONANCE STUDIES OF RADICAL ANIONS .2. AROMATIC NITRO-COMPOUNDS
AYSCOUGH, PB
WILSON, R
SARGENT, FP
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (NOV): : 5418 - &
[4] ELECTRON SPIN RESONANCE SPECTRA OF PHENYLTRIMETHYL-SILANE AND -GERMANE ANIONS - PI-BONDING BETWEEN SILICON AND GERMANIUM AND AROMATIC RING
BEDFORD, JA
BOLTON, JR
PRINCE, RH
CARRINGTON, A
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1963, 59 (481): : 53 - &
[5] BENNETT SW, 1969, J ORGANOMET CHEM, V16, P36
[6] CADOGAN JIG, 1967, ADV FREE RADICAL CHE, V2, P222
[7] ELECTRON SPIN RESONANCE SPECTRUM AND SPIN DENSITY DISTRIBUTION OF BENZYL RADICAL
CARRINGT.A
SMITH, ICP
[J]. MOLECULAR PHYSICS, 1965, 9 (02) : 137 - +
[8] ELECTRON SPIN RESONANCE STUDIES OF OXIDATION .4. SOME BENZENOID COMPOUNDS
DIXON, WT
NORMAN, ROC
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (DEC): : 4857 - &
[9] ELECTRON SPIN RESONANCE STUDIES OF OXIDATION .1. ALCOHOLS
DIXON, WT
NORMAN, ROC
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (MAY): : 3119 - &
[10] ELECTRON SPIN RESONANCE STUDIES OF TRANSIENT ALKYL RADICALS
FESSENDEN, RW
SCHULER, RH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (09) : 2147 - &

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