CHEMICAL-SHIFT CONCERTINA

被引：49

作者：

ELLETT, JD

WAUGH, JS

机构：

[1] Department of Chemistry, Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 07期

关键词：

D O I：

10.1063/1.1672422

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The phase-alternated experiment in liquids, a multiple-pulse NMR experiment capable of scaling chemical shifts, is examined theoretically and experimentally. The theory of the experiment is worked out using both the average-Hamiltonian and classical magnetic-dipole techniques, and the results from the two methods are compared. The effects of nonideal pulse cycles are discussed. Theoretical results are compared with experimental data, and a high-resolution NMR spectrum with scaled chemical shifts is presented.

引用

页码：2851 / &

共 9 条

[1] EFFECTS OF DIFFUSION ON FREE PRECESSION IN NUCLEAR MAGNETIC RESONANCE EXPERIMENTS
CARR, HY
PURCELL, EM
[J]. PHYSICAL REVIEW, 1954, 94 (03): : 630 - 638
[2] A TIME-DEPENDENT DYSON EXPANSION-NUCLEAR RESONANCE SIGNAL IN A ROTATING SINGLE CRYSTAL
EVANS, WAB
POWLES, JG
[J]. PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1967, 92 (578P): : 1046 - &
[3] ON SOME APPLICATIONS OF MAGNUS EXPANSION IN NUCLEAR MAGNETIC RESONANCE
EVANS, WAB
[J]. ANNALS OF PHYSICS, 1968, 48 (01) : 72 - &
[4] FESSENDEN RW, 1959, J CHEM PHYS, V31, P9961
[5] HAEBERLEN U, 1968, PHYS REV, V175, P175
[6] SLICHTER CP, 1963, PRINCIPLES MAGNETIC, pCH5
[7] METHOD FOR OBSERVING CHEMICAL SHIFTS IN SOLIDS
WAUGH, JS
HUBER, LM
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (05) : 1862 - &
[8] MULTIPLE-PULSE NMR EXPERIMENTS
WAUGH, JS
WANG, CH
HUBER, LM
VOLD, RL
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (02) : 662 - &
[9] EXPONENTIAL OPERATORS AND PARAMETER DIFFERENTIATION IN QUANTUM PHYSICS
WILCOX, RM
[J]. JOURNAL OF MATHEMATICAL PHYSICS, 1967, 8 (04) : 962 - &

← 1 →