HETEROCYCLIC POLYFLUORO-COMPOUNDS .17. ETHANOLYSIS OF PERFLUORO-(2-METHYL-2H-AZIRINE)

被引：9

作者：

BANKS, RE

BERRY, D

MOORE, GJ

机构：

[1] Chemistry Department, University of Manchester, Institute of Science and Technology

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 18期

关键词：

D O I：

10.1039/j39690002598

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Perfluoro-(2-methyl-2H-azirine) reacts with ethanol to give ethyl 2-ethoxy-3,3,3-trifluoro-2-hydroxy- and 3,3,3-trifluoro-2,2-dihydroxy-propionate. These esters can also be obtained by treatment of 3,3,3-trifluoro-2,2-dihydroxypropionic acid (trifluoropyruvic acid hydrate) with ethanol in the presence of hydrochloric acid.

引用

页码：2598 / &

共 13 条

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