VANADIUM(IV) AND MIXED-VALENCE VANADIUM(IV/V) OXYGEN CLUSTERS WITH NOVEL ELECTRONIC-PROPERTIES, INCLUDING THE EXAMPLES [V12AS8O40(HCO2)]N- (N = 3 OR 5)

被引：65

作者：

MULLER, A

DORING, J

BOGGE, H

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 05期

关键词：

D O I：

10.1039/c39910000273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mixed valence compounds [NHEt3]2[NH2Me2][V12As8O40(HCO2)].2H2O 1 and Na5[V12As8O40(HCO2)].18H2O 2 containing isostructual V-O clusters with encapsulated formate ions and different electron populations, and their characterization are reported; in structurally related V-O clusters spin-spin coupling increases with increasing numbers of V(iv) centres in a nearly continuous way.

引用

页码：273 / 274

页数：2

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